The photoinduced charge transfer mechanism in aligned and unaligned carbon nanotubes

Using time-resolved reflectivity measurements on unaligned and aligned bundled single-wall carbon nanotubes with a pump energy of 1.55 eV, quasi-resonant with the second Van Hove singularity of semiconducting tubes, a positive sign of the transient reflectivity is detected in unaligned nanotubes. In contrast a negative sign is detected in aligned nanotubes. This discovery addresses a long-standing question showing that in unaligned nanotubes the stronger intertube interactions favor the formation of short-lived free charge carriers in semiconducting tubes. A detailed analysis of the transient reflectivity spectral response shows that the free carriers in the photo-excited state of semiconducting tubes move towards metallic tubes in about 400 fs.     

Experimental study of mass transfer in a dense bubble swarm

We consider the liquid-side mass transfer coefficient k_L in a dense bubble swarm for a wide range of gas volume fraction (0.45%≤α_G≤16.5%). The study is performed for an air–water system in a square column. Bubble size, shape and velocity have been measured for different gas flow rates by means of a high speed camera. Gas volume fraction and bubble velocity have also been measured by a dual-tip optical probe. Both of these measurements show that the bubble vertical velocity decreases when increasing α_G in agreement with previous investigations. The mass transfer is measured from the time evolution of the dissolved oxygen concentration, which is obtained by the gassing-out method. The mass transfer coefficient is found to be very close to that of a single bubble provided the bubble Reynolds number is based on the average equivalent diameter 〈d_eq〉 and the vertical slip velocity 〈V_z〉.     

Sequential excavation,NATM and ADECO: What they have in common and how they differ

Rabcewicz, 1964, Rabcewicz, 1965 maintained that “tunnels should be driven full face whenever possible”. ADECO, which stands for “Analysis of Controlled Deformations in tunnels”, now allows us to fulfill Rabcewicz’s dream in any stress–strain condition. In order to achieve that dream and its consequent control over cost and schedule, however, NATM must be abandoned for the ADECO. The paper traces the history of the sequential excavation, NATM (as first conceived) and Analysis of Controlled Deformations (ADECO) with the aim of shedding light on the unavoidable use of sequential excavation in “soft ground”, and of highlighting advances in tunnel design and construction that have occurred in Europe after and as alternates to the NATM. The paper presents the basic concepts in the ADECO approach to design, construction and monitoring of tunnels together with some case histories, including: full face excavation for Cassia tunnel (face area > 230 m²) in sands and silts under 5 m cover below an archeological area in Rome, Italy; Tartaguille tunnel (face area > 140 m²) advanced full face in highly swelling and squeezing ground under 100 m cover where NATM led to catastrophic failure, France; and 80 km of tunnels (face area > 140 m²) advanced full face in highly squeezing/swelling ground under 500 m cover for the high-speed railway line between Bologne and Florence, Italy (turnkey contract).     

Theoretical Hypothesis of a Double Barrier Regarding the D-D Interaction in a Pd Lattice： A Possible Explanation of Cold Fusion Experiment Failures

During the past 15 years, disputable experimental evidence has built up for LERN （low energy nuclear reaction） phenomena in specialized heavy hydrogen systems. Actually, it can not be said that a new branch of science is beginning. In spite of experimental contributions, the real problem is that the theoretical statements of LERN are unknown. In this work, the authors analyze the deuteron-deuteron reactions within palladium lattice by means of the coherence theory of nuclear and condensed matter and, using this general theoretical framework accepted from ＂cold fusion scientists＂, it will be shown the low occurrence probability of fusion phenomena. In fact, in the coherence approach, the D-D potential exhibits double barrier features and, in this way, the D-D fusion is hampered.     

Sustainable simultaneous communications in ad-hoc networks using smart antenna systems

This article proposes an analytical model for evaluating the number of simultaneous communications that can be sustained by an ad-hoc network in which the nodes are equipped with fully adaptive smart antennas. The presented mathematical framework adopts realistic models for the antenna radiation pattern and the channel behavior, and is able to take into account the network topology and the characteristics of the medium access control (MAC) protocol in the spatial domain. The model is employed to investigate the impact of the spatial channel model and of the angular spread on network performance. Additionally, this article examines the influence of the transmission policy of the control and data packets of the MAC layer on the number of simultaneous communications.     

Auctioning wind power sites when environmental quality matters

In this work, we propose an index that allows a public authority to order different projects for the construction of onshore wind energy plants and that explicitly takes into account their environmental quality. Wind farm projects are defined as vectors of four attributes: the technical properties of each project, its social impact, its environmental impact, and the share of earnings that proponents offer to the collectivity in compensation for the negative externalities of the wind plant. We define an absolute index that allows the ordering of different proposals and evaluation of the acceptability of each project, providing the monetary value of each point and inducing a truthful revelation of firms' private information. Moreover, we calibrate the index on the basis of data referring to wind plants in Southern Italy and derive the corresponding iso-scoring curves.     

Rule-based intelligence for domotic environments

In the last years Home Automation systems gained new momentum, permeating many human-related environments, from homes to hospitals. The rapid evolution of such systems showed several interoperability pitfalls and a generally insufficient support for advanced user–home interaction. To tackle these emerging issues, recent research works defined the concept of Intelligent Domotic Environments (IDEs) where different automation systems, appliances and devices are integrated into a single powerful environment, capable of providing Ambient Intelligence (AmI) functionalities. IDEs represent one of the first attempts to define a framework for AmI environments based on off-the-shelf domotic systems. This paper contributes to extend IDE capabilities by supporting basic intelligence requirements through a rule-based reasoning mechanism. Starting from a formal model of IDE elements (DogOnt), rules are defined to evaluate environment properties. Property checking is done both off-line, for structural properties, i.e., properties involving the physical structure and configuration of the IDE, and on-line for properties dependent on current IDE states. Two rule languages, SWRL and JenaRules, are considered for rule formalization and their reasoning performance is evaluated by comparing two different rule engines, namely Jess and Jena. Results show that rule-based reasoning can deal with quite complex property checking, effectively addressing basic intelligence for IDEs and providing the basis for more advanced behaviors such as user adaptation and proactive interaction.     

Updating of a DRASTIC-based Method for Specific Vulnerability Assessment in Carbonate Aquifers

Abstract

Some methodological modifications are suggested to improve a DRASTIC-based method as a reliable predictor of microbial contamination in extensively fractured and subordinately karstified carbonate aquifers. These modifications will allow a better assessment of vulnerability induced by the concentrated infiltration of surface runoff in two different scenarios: (a) when the karst system is entirely located within an unsaturated aquifer and (b) when the karst system is partially located within a saturated medium. The effectiveness of the updated method has been experimentally verified by comparing the vulnerability values with the results of a hydrogeological and microbiological study at a test site.     

ADECO full-face tunnel excavation of two 260 m tubes in clays with sub-horizontal jet-grouting under minimal urban cover

With a cover of 5-30 m, a 260 m² cross-sectional area, and a 4-m wide pillar, the Cassia twin road tunnels underpass Cassia road (main road to/from Rome), the remnants of a 2000 year-old Roman villa, and two existing tunnels. Stiff silty clay dominates the alignment. According to the Analysis of Controlled DEformations (ADECO) principles, each tube was excavated full face to 260 m². Compared to Sequential Excavation Method (SEM), this highly simplifies construction, leads to construction industrialization, and allows for full control of the ground ahead of the face, which is used as a stabilization measure. In order to pre-confine the tunnel core, Trevi roto-injection technique was used to create an umbrella of overlapping sub-horizontal reinforced jet-grouting columns ahead of the face, while avoiding up heave of the ground or emptying of the columns. Stiff preliminary lining sitting on sub-horizontal jet-grouting columns, final invert close to the tunnel face, and final lining no more than 50 m behind the face ensured that the pre-confinement ahead of the tunnel face became effective confinement around the cavity. The tunnels were finished on schedule and within budget with a mere 1 cm of settlement.